Recent highlights in hemicarcerand chemistry

被引:218
作者
Warmuth, R [1 ]
Yoon, J
机构
[1] Kansas State Univ, Dept Chem, Manhattan, KS 66506 USA
[2] Silla Univ, Dept Chem, Pusan 617736, South Korea
关键词
D O I
10.1021/ar980082k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Since Donald J. Cram's first synthesis of a carcerand, which permanently entrapped a single guest molecule, many other carcerands and hemicarcerands have been synthesized and studied. Slowly, we begin to understand the role of the template in the formation of hemicarceplexes and carceplexes, why some hemi carceplexes are more stable than others, and how guests enter and exit the inner phases of molecular containers. In this Account we discuss our new insight in the chemistry of molecular containers, as well as recent highlights in through-shell chemistry and in the inner-phase stabilization of reactive intermediates.
引用
收藏
页码:95 / 105
页数:11
相关论文
共 62 条
[1]   Cycloaddition of o-benzyne to benzene and the inner phase of a hemicarcerand [J].
Beno, BR ;
Sheu, CM ;
Houk, KN ;
Warmuth, R ;
Cram, DJ .
CHEMICAL COMMUNICATIONS, 1998, (03) :301-302
[2]  
CHAPMAN OL, 1973, J AM CHEM SOC, V95, P4
[3]   Elucidation of "twistomers" in container compounds [J].
Chapman, RG ;
Sherman, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (09) :1962-1963
[4]   STUDY OF TEMPLATION AND MOLECULAR ENCAPSULATION USING HIGHLY STABLE AND GUEST-SELECTIVE SELF-ASSEMBLING STRUCTURES [J].
CHAPMAN, RG ;
SHERMAN, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (35) :9081-9082
[5]   Crystal structure and thermodynamics of reversible molecular capsules [J].
Chapman, RG ;
Olovsson, G ;
Trotter, J ;
Sherman, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (25) :6252-6260
[6]   Self-assembling capsules [J].
Conn, MM ;
Rebek, J .
CHEMICAL REVIEWS, 1997, 97 (05) :1647-1668
[7]   THE DESIGN OF MOLECULAR HOSTS, GUESTS, AND THEIR COMPLEXES (NOBEL LECTURE) [J].
CRAM, DJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08) :1009-1020
[8]  
CRAM DJ, 1991, ANGEW CHEM INT EDIT, V30, P1024, DOI 10.1002/anie.199110241
[9]   MOLECULAR CONTAINER COMPOUNDS [J].
CRAM, DJ .
NATURE, 1992, 356 (6364) :29-36
[10]   HOST-GUEST COMPLEXATION .63. CONSTRICTIVE AND INTRINSIC BINDING IN A HEMICARCERAND CONTAINING 4 PORTALS [J].
CRAM, DJ ;
BLANDA, MT ;
PAEK, K ;
KNOBLER, CB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) :7765-7773