Electronic communication in a novel five-step redox system

被引：24

作者：

Ding, L

Ma, KB

de Biani, FF

Bolte, M

Zanello, P

Wagner, M

机构：

[1] JW Goethe Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany

[2] Univ Siena, Dipartimento Chim, I-53100 Siena, Italy

[3] Univ Frankfurt, Inst Organ Chem, D-60439 Frankfurt, Germany

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 06期

关键词：

D O I：

10.1021/om000969w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ansa-ferrocene complex [1,1'-fc(Bbipy)(2)O]-(PF6)(2) {[5](PF6)(2); fc = (n(5)-C5H4)(2)Fe} has been synthesized and structurally characterized. Electronic communication between the true 2,2'-bipyridylboronium substituents was observed suggesting the reduced forms [5](+) and [5](-) to be partially delocalized redox intermediates.

引用

页码：1041 / 1043

页数：3

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