Cinchona Alkaloid-Metal Complexes: Noncovalent Porous Materials with Unique Gas Separation Properties

被引：44

作者：

Lewinski, Janusz ^{[1
,2
]}

Kaczorowski, Tomasz ^{[1
]}

Prochowicz, Daniel ^{[1
]}

Lipinska, Teodozja

Justyniak, Iwona ^{[2
]}

Kaszkur, Zbigniew ^{[2
]}

Lipkowski, Janusz ^{[2
]}

机构：

[1] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland

[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 39期

关键词：

gas separation; helical structures; metalloligands; microporous materials; supramolecular chemistry; ORGANIC FRAMEWORKS; COORDINATION POLYMERS; NANOPOROUS MATERIALS; HYDROGEN STORAGE; CRYSTAL; ADSORPTION; LIGANDS; CO2; NETWORKS; DESIGN;

D O I：

10.1002/anie.201002925

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pores for thought: Dinuclear aluminum-cinchone complexes are used to construct chiral architectures through noncovalent-interaction-driven self-assembly (see picture). The flexible desolvated material with ultramicropores is a selective adsorbent with unique properties, such as temperature-triggered adsorption of N2 and high affinities for H2, CO2, and CH4. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7035 / 7039

页数：5

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