Cinchona Alkaloid-Metal Complexes: Noncovalent Porous Materials with Unique Gas Separation Properties

被引:44
作者
Lewinski, Janusz [1 ,2 ]
Kaczorowski, Tomasz [1 ]
Prochowicz, Daniel [1 ]
Lipinska, Teodozja
Justyniak, Iwona [2 ]
Kaszkur, Zbigniew [2 ]
Lipkowski, Janusz [2 ]
机构
[1] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland
[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
gas separation; helical structures; metalloligands; microporous materials; supramolecular chemistry; ORGANIC FRAMEWORKS; COORDINATION POLYMERS; NANOPOROUS MATERIALS; HYDROGEN STORAGE; CRYSTAL; ADSORPTION; LIGANDS; CO2; NETWORKS; DESIGN;
D O I
10.1002/anie.201002925
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pores for thought: Dinuclear aluminum-cinchone complexes are used to construct chiral architectures through noncovalent-interaction-driven self-assembly (see picture). The flexible desolvated material with ultramicropores is a selective adsorbent with unique properties, such as temperature-triggered adsorption of N2 and high affinities for H2, CO2, and CH4. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7035 / 7039
页数:5
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共 67 条
  • [1] High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores
    An, Jihyun
    Geib, Steven J.
    Rosi, Nathaniel L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) : 38 - +
  • [2] Structural diversity of building-blocks in coordination framework synthesis -: combining M(NO3)2 junctions and bipyridyl ligands
    Barnett, SA
    Champness, NR
    [J]. COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) : 145 - 168
  • [3] Open-framework coordination complexes from hydrogen-bonded networks: toward host/guest complexes
    Beatty, AM
    [J]. COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) : 131 - 143
  • [4] Crystal engineering of coordination polymers using 4,4′-bipyridine as a bond between transition metal atoms
    Biradha, Kumar
    Sarkar, Madhushree
    Rajput, Lalit
    [J]. CHEMICAL COMMUNICATIONS, 2006, (40) : 4169 - 4179
  • [5] Design, chirality, and flexibility in nanoporous molecule-based materials
    Bradshaw, D
    Claridge, JB
    Cussen, EJ
    Prior, TJ
    Rosseinsky, MJ
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 273 - 282
  • [6] Crystal engineering and organometallic architecture
    Braga, D
    Grepioni, F
    Desiraju, GR
    [J]. CHEMICAL REVIEWS, 1998, 98 (04) : 1375 - 1405
  • [7] Developments in inorganic crystal engineering
    Brammer, L
    [J]. CHEMICAL SOCIETY REVIEWS, 2004, 33 (08) : 476 - 489
  • [8] Metal-organic frameworks with high capacity and selectivity for harmful gases
    Britt, David
    Tranchemontagne, David
    Yaghi, Omar M.
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (33) : 11623 - 11627
  • [9] TOWARDS A GRAMMAR OF CRYSTAL PACKING
    BROCK, CP
    DUNITZ, JD
    [J]. CHEMISTRY OF MATERIALS, 1994, 6 (08) : 1118 - 1127
  • [10] An Amine-Functionalized MIL-53 Metal-Organic Framework with Large Separation Power for CO2 and CH4
    Couck, Sarah
    Denayer, Joeri F. M.
    Baron, Gino V.
    Remy, Tom
    Gascon, Jorge
    Kapteijn, Freek
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (18) : 6326 - +