Osmium-mediated radical polymerization

被引：84

作者：

Braunecker, WA ^{[1
]}

Itami, Y ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

MACROMOLECULES | 2005年 / 38卷 / 23期

关键词：

D O I：

10.1021/ma051877r

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The ability of Osmium to mediate atom transfer radical polymerization (ATRP)) and stable free radical polymerization (SFRP) and to probe the potential interplay of these two radical polymerization mechanisms on a single metal catalysts was investigated. The polymers generated in reactions of bulk monomer at 100°C typically possessed molecular weights close to theoretical values based on conversion and were observed to follow first-order linear kinetics. Such observations indicated that the Os complex had mediated a controlled polymerization. The results show that polymerization could be mediated under directed ATRP conditions in DMF, but the solvent had an adverse effect on catalyst performance.

引用

页码：9402 / 9404

页数：3

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