Aromatization of propane over Zn/HZSM-5 catalysts prepared by chemical vapor deposition

被引：24

作者：

Kwak, BS ^{[1
]}

Sachtler, WMH ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,CTR CATALYSIS & SURFACE SCI,VN IPATIEFF LAB,EVANSTON,IL 60208

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 1996年 / 13卷 / 04期

关键词：

aromatization; propane; Zn/HZSM-5; CVD;

D O I：

10.1007/BF02705962

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc was introduced into HZSM-5 by chemical Vapor deposition (CVD) to investigate the catalytic properties of Zn/HZSM-5 for propane conversion. Irrespective of catalytic precursor or ion exchange method, protons were found to be replaced by Zn ions. However, Zn species in the zeolite were different depending on the precursors used. Although the addition of Zn decreased the intensity of the Bronsted acidity, it did not caused the apparent formation of Lewis acid sites unlike Ga/HZSM-5 catalysts. On Zn/HZSM-5, both Zn and protons intervene in propane activation step.

引用

页码：356 / 363

页数：8

共 27 条

[21]

PLANCK CJ, 1979, Patent No. 4157293

[22] GA2O3/HZSM-5 PROPANE AROMATIZATION CATALYSTS - FORMATION OF ACTIVE-CENTERS VIA SOLID-STATE REACTION [J].

PRICE, GL ;

KANAZIREV, V .

JOURNAL OF CATALYSIS, 1990, 126 (01) :267-278

[23]

Seddon D., 1990, CATAL TODAY, V6, P351, DOI [10.1016/0920-5861(90)85009-D, DOI 10.1016/0920-5861(90)85009-D]

[24]

YALETT BL, 1973, COMPREHENSIVE INORGA, V3

[25]

YANG Y, 1989, ZEOLITES CATALYSTS S

[26] CONVERSION OF N-BUTANE INTO BTX AROMATICS ON NEW HYBRID CATALYSTS [J].

YAO, J ;

LEVANMAO, R ;

DUFRESNE, L .

APPLIED CATALYSIS, 1990, 65 (02) :175-188

[27]

[No title captured]

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