Formation and in situ characterization of the first dihydrogen aqua complex:: [Ru(H2O)5(H2)]2+

被引：32

作者：

Aebischer, N ^{[1
]}

Frey, U ^{[1
]}

Merbach, AE ^{[1
]}

机构：

[1] Univ Lausanne, BCH Dorigny, Inst Chim Minerale & Analyt, CH-1015 Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a805579c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The product of the reaction between [Ru(H2O)(6)](2+) and pressurized H-2 in water is [Ru(H2O)(5)(H-2)](2+) whose nature was unambiguously demonstrated by H-1 and O-17 NMR and which is the first characterized dihydrogen aqua complex.

引用

页码：2303 / 2304

页数：2

共 13 条

[1] Trans- and cis-water reactivities in d6 octahedral ruthenium(II) pentaaqua complexes:: Experimental and density functional theory studies
Aebischer, N
Sidorenkova, E
Ravera, M
Laurenczy, G
Osella, D
Weber, J
Merbach, AE
[J]. INORGANIC CHEMISTRY, 1997, 36 (26) : 6009 - 6020
[2] The slowest water exchange at a homoleptic mononuclear metal center: Variable-temperature and variable-pressure O-17 NMR study on [Ir(H2O)(6)](3+)
Cusanelli, A
Frey, U
Richens, DT
Merbach, AE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (22) : 5265 - 5271
[3] Cusanelli T., 1997, SPECTROSC EUR, V9, P22
[4] ISOSTRUCTURAL ETA-2-DIHYDROGEN COMPLEXES [OS(NH3)5(H2)]2+,[OS(NH3)5(H2)]3+ AND THE HYDROGENATION OF ACETONE
HARMAN, WD
TAUBE, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) : 2261 - 2263
[5] MOLECULAR-HYDROGEN COMPLEXES - COORDINATION OF A SIGMA-BOND TO TRANSITION-METALS
KUBAS, GJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (03) : 120 - 128
[6] THE BINDING OF DINITROGEN TO RUTHENIUM(II) IN AQUEOUS-SOLUTION
LAURENCZY, G
HELM, L
MERBACH, AE
LUDI, A
[J]. INORGANICA CHIMICA ACTA, 1991, 189 (02) : 131 - 133
[7] QUANTITATIVE FORMATION IN WATER OF [RU(CO)(H2O)5]2+ FROM HEXAAQUARUTHENIUM(II) AND CARBON-MONOXIDE
LAURENCZY, G
HELM, L
LUDI, A
MERBACH, AE
[J]. HELVETICA CHIMICA ACTA, 1991, 74 (06) : 1236 - 1238
[8] AQUEOUS CATALYTIC DIMERIZATION OF ETHYLENE - CHARACTERIZATION OF THE REACTION INTERMEDIATES [RU(CH2=CH2)(H2O)5](TOS)2 AND [RU(CH2=CH2)2(H2O)4](TOS)2(TOS=TOLUENE-P-SULFONATE)
LAURENCZY, G
MERBACH, AE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (02) : 187 - 189
[9] DIHYDROGEN AS A COLIGAND IN SUBSTITUTION AND CIS/TRANS ISOMERIZATION-REACTIONS
LI, ZW
TAUBE, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (21) : 9506 - 9513
[10] MODULATION OF PHYSICAL AND CHEMICAL-PROPERTIES OF ETA-H-2 COMPLEXES OF OSMIUM AMMINES BY FACILE SUBSTITUTION
LI, ZW
TAUBE, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) : 8946 - 8947

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