Oils and Fats as Renewable Raw Materials in Chemistry

被引:812
作者
Biermann, Ursula [2 ]
Bornscheuer, Uwe [3 ]
Meier, Michael A. R. [1 ]
Metzger, Juergen O. [2 ]
Schaefer, Hans J. [4 ]
机构
[1] KIT, Inst Organ Chem, D-76131 Karlsruhe, Germany
[2] Carl von Ossietzky Univ Oldenburg, Inst Reine & Angew Chem, D-26129 Oldenburg, Germany
[3] Ernst Moritz Arndt Univ Greifswald, Inst Biochem, D-17487 Greifswald, Germany
[4] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
关键词
enzyme catalysis; fatty acids; homogeneous catalysis; polymers; renewable resources; OPENING METATHESIS POLYMERIZATION; ACID METHYL-ESTERS; LIPASE-CATALYZED SYNTHESIS; ACYCLIC DIENE METATHESIS; CROSS-METATHESIS; VEGETABLE-OIL; PLANT OILS; MICROBIAL-PRODUCTION; OLEIC-ACID; IMPORTANT DERIVATIVES;
D O I
10.1002/anie.201002767
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Oils and fats of vegetable and animal origin have been the most important renewable feedstock of the chemical industry in the past and in the present. A tremendous geographical and feedstock shift of oleochemical production has taken place from North America and Europe to southeast Asia and from tallow to palm oil. It will be important to introduce and to cultivate more and new oil plants containing fatty acids with interesting and desired properties for chemical utilization while simultaneously increasing the agricultural biodiversity. The problem of the industrial utilization of food plant oils has become more urgent with the development of the global biodiesel production. The remarkable advances made during the last decade in organic synthesis, catalysis, and biotechnology using plant oils and the basic oleochemicals derived from them will be reported, including, for example, omega-functionalization of fatty acids containing internal double bonds, application of the olefin metathesis reaction, and de novo synthesis of fatty acids from abundantly available renewable carbon sources.
引用
收藏
页码:3854 / 3871
页数:18
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