Nitroalkenes as precursors to the aromatic spiroketal skeleton of γ-rubromycin.: A Nef-type reaction mediated by Pearlman's catalyst

被引:38
作者
Capecchi, T [1 ]
de Koning, CB [1 ]
Michael, JP [1 ]
机构
[1] Univ Witwatersrand, Dept Chem, Ctr Mol Design, ZA-2050 Wits, South Africa
关键词
D O I
10.1016/S0040-4039(98)01046-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first synthesis of the benzannelated spiroketal core of gamma-rubromycin using Henry condensations and a novel Nef-type reaction induced by Pearlman's catalyst is described. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码:5429 / 5432
页数:4
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