New developments of sonoelectrochemistry - Electroorganic reactions under ultrasonic fields

被引：8

作者：

Atobe, M ^{[1
]}

Nonaka, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

NIPPON KAGAKU KAISHI | 1998年 / 04期

关键词：

D O I：

10.1246/nikkashi.1998.219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Effects of ultrasounds on electroorganic processes have extensively been examined in a series of Investigations. The current efficiency and/or product selectivity were found to be greatly affected by ultrasonic irradiation. From experimental and theoretical considerations, it was verified that the effects are caused by mass transport enhanced by ultrasonic cavitation in the electrode interface. In addition, highly dense and uniform polymer films could be prepared by electrooxidative polymerization under ultrasonic irradiation. As a conclusion, it is stated that ultrasounds offer a powerful and useful method for purposive reaction control in a variety of electroorganic processes.

引用

页码：219 / 230

页数：12

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Mason T.J., 1993, ADV SONOCHEMISTRY, V3

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