Synthesis and reactivity of silicon transition metal .29. Trihydridosilyl complexes of iron and ruthenium - Simple synthesis, ligand exchange reactions on metal and vibration spectroscopic analysis

被引：29

作者：

Malisch, W ^{[1
]}

Moller, S ^{[1
]}

Fey, O ^{[1
]}

Wekel, HU ^{[1
]}

Pikl, R ^{[1
]}

Posset, U ^{[1
]}

Kiefer, W ^{[1
]}

机构：

[1] UNIV WURZBURG,INST PHYS CHEM,D-97070 WURZBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 507卷 / 1-2期

关键词：

silane; iron; ruthenium; phosphine; crystal structure; silyl;

D O I：

10.1016/0022-328X(95)05757-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ferro- and ruthenio-trihydridosilanes (C(5)R(5))(OC)(2)M-SiH3 [R = H, M = Fe (3a), Ru (3b); R = Me, M = Fe (3c), Ru (3d)] are prepared via reaction of the ferro- and ruthenio-dichlorosilanes (C(5)R(5))(OC)(2)M-SiHCl2 (2a-d) with LiAlH4 in Et(2)O. Photo-induced substitution of CO can be achieved in the case of 3a with Me(3)P (4a) or Ph(3)P (4b), leading to the formation of the phosphane-substituted ferro-trihydridosilanes Cp(OC)(L)Fe-SiH3 [L = Me(3)P (5a), Ph(3)P (5b)] and Cp(Me(3)P)(2)Fe-SiH3 (6). The new silicon-transition metal complexes were characterized in detail spectroscopically (NMR, IR, Raman). The structure of 3c has been determined by X-ray structural analysis.

引用

页码：117 / 124

页数：8

共 43 条

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