Production of hydrogen from dimethyl ether

被引：169

作者：

Galvita, VV ^{[1
]}

Semin, GL ^{[1
]}

Belyaev, VD ^{[1
]}

Yurieva, TM ^{[1
]}

Sobyanin, VA ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

APPLIED CATALYSIS A-GENERAL | 2001年 / 216卷 / 1-2期

关键词：

dimethyl ether; steam reforming; hydrogen;

D O I：

10.1016/S0926-860X(01)00540-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic reaction of steam reforming of dimethyl ether (DME) to hydrogen-rich gas was studied in a fixed-bed continuous-flow reactor at a temperature of 200-360 degreesC under atmospheric pressure over a mechanical mixture of catalysts for DME hydration and for methanol steam reforming. It was found that the mechanical mixture of 12-tungstosilicoheteropolyacid deposited on gamma -Al2O3 (DME hydration catalyst) and copper deposited on SiO2 (methanol steam reforming catalyst) provided a 100% DME conversion and hydrogen outlet concentration of similar to 71 vol.% at 290 degreesC and GHSV similar to 1200 h(-1). (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：85 / 90

页数：6

共 21 条

[1] COPPER-CATALYSTS FOR THE STEAM REFORMING OF METHANOL - ANALYSIS OF THE PREPARATION VARIABLES [J].