Facile CC bond cleavage of polyynediyldiiron complexes, Fp-(CC)n-Fp [Fp=Fe(η5-C5Me5)(CO)2, n = 3, 4], with Fe2(CO)9 leading to bis(μ3-alkylidyne) complexes, Fp-CC-μ3-C-Fe3(CO)9-μ3-C-(CC)n-2-Fp*

被引：30

作者：

Akita, M ^{[1
]}

Sakurai, A ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 01期

关键词：

D O I：

10.1039/a808712a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the polyynediyldiiron complexes, Fp*-(C=C)(n)-Fp* [Fp* = Fe(eta(5)-C5Me5)(CO)(2); n = 3, 4], with Fe-2(CO)(9) at room temperature results in C=C bond cleavage to give the bis(mu(3)-alkylidyne) complexes, Fp*-C=C-mu(3)-C-Fe-3(CO)(9)- mu(3)-C-(C=C)(n-2)-F-P*, a trinuclear cluster complex sandwiched by the two conjugated (C=C)(x)-Fe systems.

引用

页码：101 / 102

页数：2

共 15 条

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Facile CC bond cleavage of polyynediyldiiron complexes, Fp*-(CC)n-Fp* [Fp*=Fe(η5-C5Me5)(CO)2, n = 3, 4], with Fe2(CO)9 leading to bis(μ3-alkylidyne) complexes, Fp*-CC-μ3-C-Fe3(CO)9-μ3-C-(CC)n-2-Fp*

Facile CC bond cleavage of polyynediyldiiron complexes, Fp-(CC)n-Fp [Fp=Fe(η5-C5Me5)(CO)2, n = 3, 4], with Fe2(CO)9 leading to bis(μ3-alkylidyne) complexes, Fp-CC-μ3-C-Fe3(CO)9-μ3-C-(CC)n-2-Fp*