Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis

被引：65

作者：

Bianchini, C ^{[1
]}

Meli, A ^{[1
]}

Oberhauser, W ^{[1
]}

机构：

[1] CNR, ICCOM, I-50132 Florence, Italy

来源：

DALTON TRANSACTIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b303502f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article addresses fundamental. mechanistic aspects related to the perfectly alternating copolymerisation of CO and ethene in MeOH through the analysis of both actual reactions catalysed by palladium(II)-diphosphine precursors and stoichiometric reactions with model compounds. Most recent in situ studies of CO/ethene copolymerisation, applying high-pressure IR and NMR techniques, have been reviewed and commented.

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页码：2627 / 2635

页数：9

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