Ethene and styrene insertion into the Pd-acyl bond of [Pd(COMe)(P∧N)(solv)]O3SCF3 and its role in the copolymerisation of olefins with carbon monoxide

被引：52

作者：

Aeby, A ^{[1
]}

Consiglio, G ^{[1
]}

机构：

[1] ETH Zentrum, Tech Chem Lab, CH-8092 Zurich, Switzerland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 05期

关键词：

D O I：

10.1039/a900668k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Styrene has higher productivity than ethene during copolymerisation with carbon monoxide using [Pd(COCH3)((PN)-N-boolean AND)(solv)]O3SCF3 (where (PN)-N-boolean AND is a phosphanyldihydrooxazole ligand), while ethene, not styrene, is preferentially enchained during the terpolymerisation probably reflecting the different reactivity of the two possible alkyl intermediates toward carbon monoxide insertion.

引用

页码：655 / 656

页数：2

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