mpg-C3N4-Catalyzed Selective Oxidation of Alcohols Using O2 and Visible Light

被引：899

作者：

Su, Fangzheng ^{[2
,3
]}

Mathew, Smitha C. ^{[1
]}

Lipner, Grzegorz ^{[1
]}

Fu, Xianzhi ^{[2
]}

Antonietti, Markus ^{[3
]}

Blechert, Siegfried ^{[1
]}

Wang, Xinchen ^{[2
,3
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[2] Fuzhou Univ, Int Joint Lab, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China

[3] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 46期

关键词：

PHOTOREDOX CATALYSIS; TIO2; PHOTOCHEMISTRY; PHOTOCATALYSIS; NANOPARTICLES; PHOTOPHYSICS; ALDEHYDES; OXYGEN; WATER; IONS;

D O I：

10.1021/ja102866p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mesoporous carbon nitride (mpg-C3N4) polymer can function as a metal-free photocatalyst to activate O-2 for the selective oxidation of benzyl alcohols with visible light, avoiding the cost, toxicity, and purification problems associated with corresponding transition-metal systems. By combining the surface basicity and semiconductor functions of mpg-C3N4, the photocatalytic system can realize a high catalytic selectivity to generate benzaldehyde. The metal-free photocatalytic system also selectively converts other alcohol substrates to their corresponding aldehydes/ketones, demonstrating a potential pathway of accessing traditional mild radical chemistry with nitroxyl radicals.

引用

页码：16299 / 16301

页数：3

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