Easy and partial hydrogenation of aromatic carbonyls to benzyl alcohols using Pd/C(en)-catalyst

被引：54

作者：

Sajiki, H ^{[1
]}

Hattori, K ^{[1
]}

Hirota, K ^{[1
]}

机构：

[1] Gifu Pharmaceut Univ, Med Chem Lab, Gifu 5028585, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 24期

关键词：

D O I：

10.1039/a807486k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Although 10% Pd/C catalyzed hydrogenolysis of aromatic ketones and aldehydes readily affords methylene compounds via intermediary benzyl alcohols, the employment of 10% Pd/C-ethylenediamine complex [Pd/C(en)] as a catalyst eased the formation of benzyl alcohols.

引用

页码：4043 / 4044

页数：2

共 18 条

[1]

[Anonymous], 1996, REDUCTIONS ORGANIC C

[2] EFFICIENT RHODIUM-CATALYZED HYDROGENATION OF ALDEHYDES AND KETONES [J].