Coordination polymers with chelidonate (4-oxo-4H-pyran-2,6-dicarboxylate) anions and dmso: [Zn(chel)(dmso)2] and linkage isomers of [Co(chel)(dmso)(OH2)3]•H2O

被引：4

作者：

Belen Lago, Ana ^{[1
]}

Carballo, Rosa ^{[1
]}

Fernandez-Hermida, Nuria ^{[1
]}

Rodriguez-Hermida, Sabina ^{[1
]}

Vazquez-Lopez, Ezequiel M. ^{[1
]}

机构：

[1] Univ Vigo, Fac Quim, Dept Quim Inorgan, E-36310 Vigo, Galicia, Spain

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2011年 / 1003卷 / 1-3期

关键词：

Coordination polymers; Metallosupramolecular chemistry; Linkage isomerism; Chelidonate ligand; 4-oxo-4H-pyran-2,6-dicarboxylic acid; Crystal structure; CRYSTAL-STRUCTURE; COMPLEXES; ZN(II);

D O I：

10.1016/j.molstruc.2011.07.050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recrystallization from dmso of the previously prepared compound [Co(chel)(H2O)(4)] (chel = 4-oxo-4H-pyran-2,6-dicarboxylate), led to the new one-dimensional coordination polymers 1a and 1b, which are linkage isomers of formula [Co(chel)(dmso)(OH2)(3)]center dot H2O. Also the recrystallization from dmso of the previously prepared [Zn(chel)(H2O)(2)] allow the isolation of the one-dimensional coordination polymer [Zn(chel)(dmso)(2)] (2). [Co(chel)(H2O)(4)] was characterized by elemental analysis, IR and electronic spectroscopy, magnetic measurements at room temperature and thermogravimetric analysis. X-ray single crystal diffraction of 1a, 1b and 2 showed the coordinative behavior of the chelidonate ligand in each compound as well as the different participation of this ligand in the corresponding metallosupramolecular organization. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：121 / 128

页数：8

共 32 条

[1] Mononuclear discrete complexes and coordination polymers based on metal(II) chelidonate complexes with aromatic N,N-chelatingligands [J].

Belen Lago, Ana ;

Carballo, Rosa ;

Fernandez-Hermida, Nuria ;

Vazquez-Lopez, Ezequiel M. .

CRYSTENGCOMM, 2011, 13 (03) :941-951

[2] ESCHERICHIA-COLI DIHYDRODIPICOLINATE SYNTHASE - CHARACTERIZATION OF THE IMINE INTERMEDIATE AND THE PRODUCT OF BROMOPYRUVATE TREATMENT BY ELECTROSPRAY MASS-SPECTROMETRY [J].

BORTHWICK, EB ;

CONNELL, SJ ;

TUDOR, DW ;

ROBINS, DJ ;

SHNEIER, A ;

ABELL, C ;

COGGINS, JR .

BIOCHEMICAL JOURNAL, 1995, 305 :521-524

[3] New software for searching the Cambridge Structural Database and visualizing crystal structures [J].

Bruno, IJ ;

Cole, JC ;

Edgington, PR ;

Kessler, M ;

Macrae, CF ;

McCabe, P ;

Pearson, J ;

Taylor, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 :389-397

[4] Structure and bonding in metal sulfoxide complexes: an update [J].

Calligaris, M .

COORDINATION CHEMISTRY REVIEWS, 2004, 248 (3-4) :351-375

[5] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

[6] Crystal structure of triaqua(4-oxo-4H-pyran-2,6-dicarboxylato)-(1,10-phenanthroline)manganese(II) monohydrate, [Mn(H2O)3(C7H2O6)(C12H8N2)] • H2O [J].

Chen, Jiu Cun .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2009, 224 (01) :29-30

[7]

Chevallier A., 1996, ENCY MED PLANTS

[8] Experimental observation of supramolecular carbonyl-π/π-π/π-carbonyl and carbonyl-π/π-π/π-anion assemblies supported by theoretical studies [J].

Choudhury, Somnath Ray ;

Gamez, Patrick ;

Robertazzi, Arturo ;

Chen, Chih-Yuan ;

Lee, Hon Man ;

Mukhopadhyay, Subrata .

CRYSTAL GROWTH & DESIGN, 2008, 8 (10) :3773-3784

[9] 3D zinc(II) coordination polymers built up by triazole and benzene-polycarboxylate anions: Synthesis, crystal structure, thermal and photoluminescence characterization [J].

Chowdhuri, Durga Sankar ;

Rana, Abhinandan ;

Bera, Madhusudan ;

Zangrando, Ennio ;

Dalai, Sudipta .

POLYHEDRON, 2009, 28 (11) :2131-2136

[10]

Damhus T., 2005, NOMENCLATURE INORGAN

← 1 2 3 4 →