Continuous carbide-derived carbon films with high volumetric capacitance

被引:160
作者
Heon, Min [1 ]
Lofland, Samuel [2 ]
Applegate, James [2 ]
Nolte, Robert [2 ]
Cortes, Emma [2 ]
Hettinger, Jeffrey D. [2 ]
Taberna, Pierre-Louis [3 ]
Simon, Patrice [3 ]
Huang, Peihua [3 ,4 ]
Brunet, Magali [4 ]
Gogotsi, Yury [1 ]
机构
[1] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[2] Rowan Univ, Dept Phys & Astron, Glassboro, NJ USA
[3] Univ Toulouse 3, CIRIMAT, CNRS, UMR 5085, F-31062 Toulouse, France
[4] Univ Toulouse, CNRS, LAAS, Toulouse, France
关键词
RAMAN-SPECTROSCOPY; TITANIUM CARBIDE;
D O I
10.1039/c0ee00404a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Monolithic porous carbon film has a great potential for integrated supercapacitors due to no polymer binder, reduced macropore volume, and good adhesion between current collector and active material. It is demonstrated that continuous carbide-derived carbon (CDC) films can be synthesized on various substrates by dry etching. CDC films show high volumetric capacitance of similar to 180 F cm(-3) in 1.5 M TEABF(4)/acetonitrile electrolyte.
引用
收藏
页码:135 / 138
页数:4
相关论文
共 22 条
[1]  
[Anonymous], 1999, ELECTROCHEMICAL SUPE
[2]   Formation of carbide-derived carbon on β-silicon carbide whiskers [J].
Cambaz, ZG ;
Yushin, GN ;
Gogotsi, Y ;
Vyshnyakova, KL ;
Pereselentseva, LN .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (02) :509-514
[3]  
Chmiola J, 2006, SCIENCE, V313, P1760, DOI 10.1126/science/1132195
[4]   Desolvation of ions in subnanometer pores and its effect on capacitance and double-layer theory [J].
Chmiola, John ;
Largeot, Celine ;
Taberna, Pierre-Louis ;
Simon, Patrice ;
Gogotsi, Yury .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3392-3395
[5]   Monolithic Carbide-Derived Carbon Films for Micro-Supercapacitors [J].
Chmiola, John ;
Largeot, Celine ;
Taberna, Pierre-Louis ;
Simon, Patrice ;
Gogotsi, Yury .
SCIENCE, 2010, 328 (5977) :480-483
[6]   Titanium carbide derived nanoporous carbon for energy-related applications [J].
Dash, Ranjan ;
Chmiola, John ;
Yushin, Gleb ;
Gogotsi, Yury ;
Laudisio, Giovanna ;
Singer, Jonathan ;
Fischer, John ;
Kucheyev, Sergei .
CARBON, 2006, 44 (12) :2489-2497
[7]  
Fedorov NF, 1998, RUSS J APPL CHEM+, V71, P600
[8]   Raman spectroscopy of amorphous, nanostructured, diamond-like carbon, and nanodiamond [J].
Ferrari, AC ;
Robertson, J .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2004, 362 (1824) :2477-2512
[9]  
GORDEEV SK, 1994, ZH PRIKL KHIM, V66, P1080
[10]   Carbide-derived carbon membrane [J].
Hoffman, Elizabeth N. ;
Yushin, Gleb ;
Wendler, Bogdan G. ;
Barsoum, Michel W. ;
Gogotsi, Yury .
MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (02) :587-591