Concentration dependence of the 1H- and 29Si-NMR chemical shifts of tetramethyldisiloxanediol in deuterated chloroform

被引：4

作者：

Kretchmer, A ^{[1
]}

Backer, M ^{[1
]}

机构：

[1] Dow Corning Ltd, Barry CF63 2YL, Vale Glamorgan, Wales

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 628卷 / 02期

关键词：

NMR spectroscopy; Organosilicon chemistry; silanol;

D O I：

10.1016/S0022-328X(01)00788-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In literature, NMR chemical shifts of protons and silicon atoms in silanols have always been discussed with respect to the polarity of the solvents used. In this paper, chemical shift values of tetramethyldisiloxartediol M-2(OH) are presented with regard to their change in dependence on concentration in deuterated chloroform and on temperature. These values are compared to values found in solid state NMR spectroscopy. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：233 / 240

页数：8

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