A Shape-Persistent Organic Molecular Cage with High Selectivity for the Adsorption of CO2 over N2

被引：228

作者：

Jin, Yinghua ^{[1
]}

Voss, Bret A. ^{[2
]}

Noble, Richard D. ^{[2
]}

Zhang, Wei ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

[2] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 36期

关键词：

cage compounds; CO2; adsorption; dynamic covalent chemistry; porous materials; Schiff bases; X-RAY; FRAMEWORK; NETWORKS; BINDING; MACROCYCLES; CRYSTALLINE; SEPARATIONS; MEMBRANE; POLYMERS; METHANE;

D O I：

10.1002/anie.201001517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon capture in an organic cage: A shape-persistent, organic prismatic molecular cage (see structure) was synthesized in one step and high yield from readily accessible starting materials through dynamic covalent chemistry. The resulting cage molecule exhibited high selectivity for the adsorption of CO2 over N2 and thus shows promise as a carbon-capture material. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6348 / 6351

页数：4

共 54 条

[1]

[Anonymous], 2006, ANGEW CHEM-GER EDIT

[2]

[Anonymous], ANGEW CHEM

[3] X-RAY STUDIES OF INTERACTION OF CO2 WITH HUMAN DEOXYHEMOGLOBIN [J].

ARNONE, A .

NATURE, 1974, 247 (5437) :143-145

[4]

Atwood, 2006, ANGEW CHEM, V118, P6656

[5] Storage of methane and freon by interstitial van der Waals confinement [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

SCIENCE, 2002, 296 (5577) :2367-2369

[6] Room-Temperature Ionic Liquids and Composite Materials: Platform Technologies for CO2 Capture [J].

Bara, Jason E. ;

Camper, Dean E. ;

Gin, Douglas L. ;

Noble, Richard D. .

ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (01) :152-159

[7] A microporous metal-organic framework for separation of CO2/N2 and CO2/CH4 by fixed-bed adsorption [J].

Bastin, Laurent ;

Barcia, Patrick S. ;

Hurtado, Eric J. ;

Silva, Jose A. C. ;

Rodrigues, Alirio E. ;

Chen, Banglin .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (05) :1575-1581

[8] Molecular tectonics. Porous hydrogen-bonded networks with unprecedented structural integrity [J].

Brunet, P ;

Simard, M ;

Wuest, JD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) :2737-2738

[9]

Christinat N., 2008, ANGEW CHEM, V120, P1874

[10] Multicomponent assembly of boronic acid based macrocycles and cages [J].

Christinat, Nicolas ;

Scopelliti, Rosario ;

Severin, Kay .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (10) :1848-1852

← 1 2 3 4 5 6 →