Measurement and correlation of liquid-liquid equilibria of two imidazolium ionic liquids with thiophene and methylcyclohexane

被引：47

作者：

Alonso, Luisa ^{[1
]}

Arce, Alberto ^{[1
]}

Francisco, Maria ^{[1
]}

Soto, Ana ^{[1
]}

机构：

[1] Univ Santiago de Compostela, Dept Chem Engn, E-15782 Santiago De Compostela, Spain

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2007年 / 52卷 / 06期

关键词：

D O I：

10.1021/je700362q

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Equilibrium studies on the extraction of thiophene from its mixtures with methylcyclohexane using two imidazolium ionic liquids have been carried out. LLE data were obtained for mixtures of 1-methyl-3-octylimidazolium bis-[trifluoromethylsulfonyl]imide or 1-methyl-3-octylimidazolium tetrafluoroborate with thiophene and methylcyclohexane at atmospheric pressure and 298.15 K. Tie-line compositions were correlated using the NRTL equation, but considerable deviations from experimental data were found at high concentrations of thiophene. Distribution coefficients and selectivities were evaluated.

引用

页码：2409 / 2412

页数：4

共 18 条

[1]

STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].

ABRAMS, DS ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (01) :116-128

[2]

Physical and excess properties for binary mixtures of 1-methyl-3-octylimidazolium tetrafluoroborate, [Omim][BF4], ionic liquid with different alcohols [J].

Arce, A ;

Rodil, E ;

Soto, A .

JOURNAL OF SOLUTION CHEMISTRY, 2006, 35 (01) :63-78

[3]

Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[4]

Hydrophobic, highly conductive ambient-temperature molten salts (vol 35, pg 1168, 1996) [J].

Bonhote, P ;

Dias, AP ;

Armand, M ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1998, 37 (01) :166-166

[5]

Small-angle X-ray scattering studies of liquid crystalline 1-alkyl-3-methylimidazolium salts [J].

Bradley, AE ;

Hardacre, C ;

Holbrey, JD ;

Johnston, S ;

McMath, SEJ ;

Nieuwenhuyzen, M .

CHEMISTRY OF MATERIALS, 2002, 14 (02) :629-635

[6]

Ionic liquids: Innovative fluids for chemical processing [J].

Brennecke, JF ;

Maginn, EJ .

AICHE JOURNAL, 2001, 47 (11) :2384-2389

[7]

PURIFICATION AND PROPERTIES OF 10 ORGANIC SULFUR COMPOUNDS [J].

HAINES, WE ;

HELM, RV ;

BAILEY, CW ;

BALL, JS .

JOURNAL OF PHYSICAL CHEMISTRY, 1954, 58 (03) :270-278

[8]

Kubota F, 2006, SOLVENT EXTR RES DEV, V13, P23

[9]

Ionic liquids - Progress on the fundamental issues [J].

MacFarlane, Douglas R. ;

Seddon, Kenneth R. .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2007, 60 (01) :3-5

[10]

An overview of hydrodesulfurization and hydrodenitrogenation [J].

Mochida, I ;

Choi, KH .

JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2004, 47 (03) :145-163

← 1 2 →