Relayed anisotropy correlation NMR: Determination of dihedral angles in solids

被引：92

作者：

Ishii, Y ^{[1
]}

Terao, T ^{[1
]}

Kainosho, M ^{[1
]}

机构：

[1] TOKYO METROPOLITAN UNIV,FAC SCI,DEPT CHEM,TOKYO 19203,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 256卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(96)00426-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A two-dimensional solid-state NMR method is proposed for determining the mutual orientation of the two interaction tensors in each of which a different chemical group participates, from which information on the dihedral angle can be the C-13(1) chemical shift anisotropy and the C-13(2)-H-1 dipolar coupling via polarization transfer. The O-C-1-C-2-H dihedral angle as well as the orientation of the C-13(1) chemical shift tensor were determined from the spectrum.

引用

页码：133 / 140

页数：8