Encapsulation of Mono- or Bimetal Nanoparticles Inside Metal-Organic Frameworks via In situ Incorporation of Metal Precursors

被引：81

作者：

Chen, Liyu ^{[1
]}

Chen, Xiaodong ^{[1
]}

Liu, Hongli ^{[1
]}

Li, Yingwei ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

SMALL | 2015年 / 11卷 / 22期

基金：

中国国家自然科学基金;

关键词：

heterogeneous catalysis; metal-organic frameworks; nanoparticles; encapsulation; OXYGEN REDUCTION; SYNERGISTIC CATALYSIS; SELECTIVE CATALYSIS; COUPLING REACTIONS; CASCADE REACTIONS; HYDROGEN STORAGE; PD NANOPARTICLES; SUZUKI-MIYAURA; FORMIC-ACID; EFFICIENT;

D O I：

10.1002/smll.201403599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile, in situ metal precursor incorporation strategy is established for good control over the location and composition of metal nanoparticles within metal-organic frameworks (MOFs). This one-step metal precursor incorporation route is successfully applied to the fabrication of ultrafine Pd, Ni, and PdNi alloys to be selectively encapsulated inside the pores of MOFs, achieving superior catalytic activity and stability in the hydrogenation of nitrobenzene. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2642 / 2648

页数：7

共 72 条

[1] Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal-Organic Framework: A Double Solvents Approach [J].

Aijaz, Arshad ;

Karkamkar, Abhi ;

Choi, Young Joon ;

Tsumori, Nobuko ;

Roennebro, Ewa ;

Autrey, Tom ;

Shioyama, Hiroshi ;

Xu, Qiang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (34) :13926-13929

[2]

Armstrong G., 2013, NAT CHEM, V5, P809

[3] Pd nanoparticles for C-C coupling reactions [J].

Balanta, Angelica ;

Godard, Cyril ;

Claver, Carmen .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (10) :4973-4985

[4] Metal Insertion in a Microporous Metal-Organic Framework Lined with 2,2′-Bipyridine [J].

Bloch, Eric D. ;

Britt, David ;

Lee, Chain ;

Doonan, Christian J. ;

Uribe-Romo, Fernando J. ;

Furukawa, Hiroyasu ;

Long, Jeffrey R. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (41) :14382-14384

[5] Maximum Noble-Metal Efficiency in Catalytic Materials: Atomically Dispersed Surface Platinum [J].

Bruix, Albert ;

Lykhach, Yaroslava ;

Matolinova, Iva ;

Neitzel, Armin ;

Skala, Tomas ;

Tsud, Nataliya ;

Vorokhta, Mykhailo ;

Stetsovych, Vitalii ;

Sevcikova, Klara ;

Myslivecek, Josef ;

Fiala, Roman ;

Vaclavu, Michal ;

Prince, Kevin C. ;

Bruyere, Stephanie ;

Potin, Valerie ;

Illas, Francesc ;

Matolin, Vladimir ;

Libuda, Joerg ;

Neyman, Konstantin M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (39) :10525-10530

[6] Highly Active and Selective Catalysis of Bimetallic Rh3Ni1 Nanoparticles in the Hydrogenation of Nitroarenes [J].

Cai, Shuangfei ;

Duan, Haohong ;

Rong, Hongpan ;

Wang, Dingsheng ;

Li, Linsen ;

He, Wei ;

Li, Yadong .

ACS CATALYSIS, 2013, 3 (04) :608-612

[7] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[8] One-pot synthesis of Pd@MOF composites without the addition of stabilizing agents [J].

Chen, Liyu ;

Chen, Huirong ;

Li, Yingwei .

CHEMICAL COMMUNICATIONS, 2014, 50 (94) :14752-14755

[9] Metal-organic framework encapsulated Pd nanoparticles: towards advanced heterogeneous catalysts [J].

Chen, Liyu ;

Chen, Huirong ;

Luque, Rafael ;

Li, Yingwei .

CHEMICAL SCIENCE, 2014, 5 (10) :3708-3714

[10] A molecular Pd(II) complex incorporated into a MOF as a highly active single-site heterogeneous catalyst for C-Cl bond activation [J].

Chen, Liyu ;

Rangan, Sylvie ;

Li, Jing ;

Jiang, Huanfeng ;

Li, Yingwei .

GREEN CHEMISTRY, 2014, 16 (08) :3978-3985

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