Unequivocal assignment of the fullerene carbons of diethyl 1,2-methano[60]fullerene 61,61-dicarboxylate using 2D INADEQUATE NMR spectroscopy

被引：14

作者：

Burley, GA

Keller, PA

Pyne, SG

Ball, GE

机构：

[1] Univ Wollongong, Dept Chem, Wollongong, NSW 2522, Australia

[2] Univ New S Wales, NMR Facil, Sydney, NSW 2052, Australia

[3] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 2001年 / 39卷 / 08期

关键词：

NMR; C-13; 2D INADEQUATE; fullerene;

D O I：

10.1002/mrc.879

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Assignment of all carbons of the [60]fullerene sphere of diethyl 1,2-methnano[60]fullerene 61,61-dicarboxylate using 2D INADEQUATE NMR spectroscopy is described. Acquiring the INADEQUATE data with small spectral widths and optional F-1 folding with States-TPPI phase implementation provides a convenient route to high-resolution data. A description of the topology of the [60]fullerene sphere and its comparison with x-ray crystallographic analysis is also presented. Copyright (C) 2001 John Wiley & Sons, Ltd.

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收藏

页码：466 / 470

页数：5

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