Structure and properties of Ti-Al-Y-N coatings deposited from filtered vacuum-arc plasma

被引:35
作者
Belous, V. A. [1 ]
Vasyliev, V. V. [1 ]
Goltvyanytsya, V. S.
Goltvyanytsya, S. K.
Luchaninov, A. A. [1 ]
Reshetnyak, E. N. [1 ]
Strel'nitskij, V. E. [1 ]
Tolmacheva, G. N. [1 ]
Danylina, O.
机构
[1] Natl Sci Ctr, Kharkov Phys & Technol Inst, Kharkov, Ukraine
关键词
Coatings; Vacuum-arc; Filtered plasma; Nitrides; Titanium-aluminum; IMMERSION ION-IMPLANTATION; ALUMINUM NITRIDE FILMS; HARD COATINGS; CUTTING TOOLS; MICROSTRUCTURE; STRESS; TIALN;
D O I
10.1016/j.surfcoat.2011.09.061
中图分类号
TB3 [工程材料学];
学科分类号
082905 [生物质能源与材料];
摘要
Ti(0.5)Al(0.5)N coatings with a small amount of Y (up to 1 at.%) were deposited by filtered vacuum arc plasma at pulsed high voltage negative substrate bias potential with amplitude up to 2.5 kV and their microstructure was studied. X-ray fluorescence analysis showed that this deposition method allows ensuring well the conformity of the elemental composition of the metallic components of cathodes and films. X-ray diffraction measurements of the films with yttrium revealed a solid solution (Ti.Al)N phase with a cubic NaCl-type structure as the only crystalline phase. The films deposited with an amplitude of the substrate bias potential in the range of 1-1.5 kV were characterized by a strong axial texture [110] In these films an increase of the yttrium content leads to the reduction of the nitride lattice parameter and growth of coherent scattering zone dimension as well as to a decrease of the surface roughness. Coatings containing 1 at.% Y exhibited high hardness of 32-36 GPa and oxidation resistance. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1720 / 1726
页数:7
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