A versatile method for the conversion of aldoximes to nitriles using silica gel/thionyl chloride

被引:7
作者
Kazemi, F [1 ]
Kiasat, AR [1 ]
Fadavipoor, E [1 ]
机构
[1] Chamran Univ, Coll Sci, Chem Dept, Ahvaz, Iran
关键词
aldoxime; nitrile; silica gel; thionyl chloride;
D O I
10.1080/10426500490262586
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A simple convenient procedure for dehydration of aldoximes has been developed using silica gel/thionyl chloride in heterogeneous conditions. The method has been found to be effective for a wide range of aromatic oximes.
引用
收藏
页码:433 / 436
页数:4
相关论文
共 16 条
[1]  
Das B, 2000, SYNLETT, P1599
[2]   Improved efficient conversion of aldehydes to nitriles via their N,N-dimethyl hydrazones [J].
Kamal, A ;
Arifuddin, M ;
Rao, NV .
SYNTHETIC COMMUNICATIONS, 1998, 28 (24) :4507-4512
[3]  
KAZEMI F, 2003, INDIAN J CHEM B
[4]   Na2SO3/SOCl2, an efficient reagent for the dehydration of aldoximes to nitriles [J].
Kiasat, AR ;
Kazemi, F ;
Khosravian, F .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (06) :1377-1383
[5]   DI-2-PYRIDYL SULFITE - A NEW USEFUL REAGENT FOR THE PREPARATION OF N-SULFINYLAMINES, NITRILES, ISOCYANIDES, AND CARBODIIMIDES UNDER MILD CONDITIONS [J].
KIM, S ;
YI, KY .
TETRAHEDRON LETTERS, 1986, 27 (17) :1925-1928
[6]  
Lai GF, 2001, SYNLETT, P230
[7]   Tetrachloropyridine: A new reagent for the dehydration of aldoximes under microwave [J].
Lingaiah, N ;
Narender, R .
SYNTHETIC COMMUNICATIONS, 2002, 32 (15) :2391-2394
[8]  
MAI K, 1986, SYNTHESIS-STUTTGART, P1037
[9]   Facile and highly selective monoacylation of symmetric diols adsorbed on silica gel with acetyl chloride [J].
Ogawa, H ;
Amano, M ;
Chihara, T .
CHEMICAL COMMUNICATIONS, 1998, (04) :495-496
[10]  
OGAWA H, 1996, PETROTECH, V19, P404