Sampsoniones C-H, a unique family of polyprenylated benzophenone derivatives with the novel tetracyclo[7.3.1.13,11.03,7]tetradecane-2,12,14-trione skeleton, from Hypericum sampsonii (Guttiferae)

被引:67
作者
Hu, LH [1 ]
Sim, KY [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore
关键词
D O I
10.1016/S0040-4039(98)02366-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The structures of sampsoniones C-H, isolated from the aerial parts of Hypericum sampsonii, have been elucidated by extensive analysis of 2 D NMR. Sampsoniones C-H are the first polyprenylated benzophenone derivatives with a unique caged tetracyclo[7.3.1.1(3,11).0(3,7)]tetradecane-2,12,14-trione skeleton. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:759 / 762
页数:4
相关论文
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[2]  
GENEIVE EH, 1995, TETRAHEDRON LETT, V36, P4575
[3]  
GENEIVE EH, 1996, TETRAHEDRON LETT, V37, P8663
[4]   Complex caged polyisoprenylated benzophenone derivatives, sampsoniones A and B, from Hypericum sampsonii [J].
Hu, LH ;
Sim, KY .
TETRAHEDRON LETTERS, 1998, 39 (43) :7999-8002