Origin of green luminescence in ZnO thin film grown by molecular-beam epitaxy

被引:398
作者
Heo, YW
Norton, DP
Pearton, SJ
机构
[1] Univ Florida, Dept Mat Sci Engn, Gainesville, FL 32611 USA
[2] Kyungpook Natl Univ, Dept Inorgan Mat Engn, Taegu 702701, South Korea
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2064308
中图分类号
O59 [应用物理学];
学科分类号
摘要
The properties of ZnO films grown by molecular-beam epitaxy are reported. The primary focus was on understanding the origin of deep-level luminescence. A shift in deep-level emission from green to yellow is observed with reduced Zn pressure during the growth. Photoluminescence and Hall measurements were employed to study correlations between deep-level/near-band-edge emission and carrier density. With these results, we suggest that the green emission is related to donor-deep acceptor (Zn vacancy V-Zn(-)) and the yellow to donor- deep acceptor (oxygen vacancy, O-i(-)). (c) 2005 American Institute of Physics.
引用
收藏
页数:6
相关论文
共 22 条
[1]   Room temperature excitonic stimulated emission from zinc oxide epilayers grown by plasma-assisted MBE [J].
Bagnall, DM ;
Chen, YF ;
Shen, MY ;
Zhu, Z ;
Goto, T ;
Yao, T .
JOURNAL OF CRYSTAL GROWTH, 1998, 184 :605-609
[2]   Plasma assisted molecular beam epitaxy of ZnO on c-plane sapphire: Growth and characterization [J].
Chen, YF ;
Bagnall, DM ;
Koh, HJ ;
Park, KT ;
Hiraga, K ;
Zhu, ZQ ;
Yao, T .
JOURNAL OF APPLIED PHYSICS, 1998, 84 (07) :3912-3918
[3]   Luminescence and nonradiative deactivation of excited states involving oxygen defect centers in polycrystalline ZnO [J].
Egelhaaf, HJ ;
Oelkrug, D .
JOURNAL OF CRYSTAL GROWTH, 1996, 161 (1-4) :190-194
[4]   INITIAL STEPS OF INTERFACE FORMATION - SURFACE-STATES AND THERMODYNAMICS [J].
GOPEL, W .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1979, 16 (05) :1229-1235
[5]   ZnO thin films prepared by remote plasma-enhanced CVD method [J].
Haga, K ;
Kamidaira, M ;
Kashiwaba, Y ;
Sekiguchi, T ;
Watanabe, H .
JOURNAL OF CRYSTAL GROWTH, 2000, 214 :77-80
[6]   Transport properties of phosphorus-doped ZnO thin films [J].
Heo, YW ;
Park, SJ ;
Ip, K ;
Pearton, SJ ;
Norton, DP .
APPLIED PHYSICS LETTERS, 2003, 83 (06) :1128-1130
[7]   ELECTRON SPIN RESONANCE STUDIES OF DONORS AND ACCEPTORS IN ZNO [J].
KASAI, PH .
PHYSICAL REVIEW, 1963, 130 (03) :989-&
[8]   Green luminescent center in undoped zinc oxide films deposited on silicon substrates [J].
Lin, BX ;
Fu, ZX ;
Jia, YB .
APPLIED PHYSICS LETTERS, 2001, 79 (07) :943-945
[9]   POINT-DEFECTS AND LUMINESCENCE-CENTERS IN ZINC-OXIDE AND ZINC-OXIDE DOPED WITH MANGANESE [J].
LIU, M ;
KITAI, AH ;
MASCHER, P .
JOURNAL OF LUMINESCENCE, 1992, 54 (01) :35-42
[10]   Recent advances in ZnO materials and devices [J].
Look, DC .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2001, 80 (1-3) :383-387