Selective oxidation of alkenes catalyzed by di-iron-substituted silicotungstate with highly efficient utilization of hydrogen peroxide

被引：30

作者：

Mizuno, N ^{[1
]}

Nozaki, C ^{[1
]}

Kiyoto, I ^{[1
]}

Misono, M ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF CATALYSIS | 1999年 / 182卷 / 01期

关键词：

di-iron-substituted silicotungstate; epoxidation; high efficiency; hydrogen peroxide;

D O I：

10.1006/jcat.1998.2369

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidation reactions of alkenes with hydrogen peroxide were catalyzed by di-iron-substituted silicotungstate, gamma-SiW10{Fe(OH2)}(2) O-38(6-), with a high efficiency of hydrogen peroxide utilization. The efficiency of hydrogen peroxide utilization reached up to ca. 100% for the epoxidation of cyclooctene catalyzed by the di-iron-substituted silicotungstate. Not only cyclooctene but also 2-octene and cyclohexene were oxidized with a high efficiency of hydrogen peroxide utilization. The gamma-SiW10{Fe(OH2)}(2)O-38(6-) silicotungstate showed the highest efficiency of hydrogen peroxide utilization and conversion among di-transition-metal- and iron-substituted silicotungstates. (C) 1999 Academic Press.

引用

页码：285 / 288

页数：4

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