Fluorination of diamond surfaces by irradiation of perfluorinated alkyl iodides

被引：56

作者：

Smentkowski, VS ^{[1
]}

Yates, JT ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,CTR SURFACE SCI,PITTSBURGH,PA 15260

来源：

SCIENCE | 1996年 / 271卷 / 5246期

关键词：

D O I：

10.1126/science.271.5246.193

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A facile method for chemically functionalizing diamond surfaces has been developed using x-ray irradiation of perfluoroalkyl iodide layers on the surface. Perfluoroalkyl radicals chemically bond to the diamond surface and can be thermally decomposed to produce strongly bound surface C-F bonds that are stable at high temperatures.

引用

页码：193 / 195

页数：3