Recent developments in chiral polynitrogenated synthetic receptors for anions

被引:7
作者
Alfonso, Ignacio [1 ]
机构
[1] CSIC, IIQAB, Dept Quim Organ Biol, E-08034 Barcelona, Spain
关键词
molecular recognition; anion; chiral receptor; stereoselective; nitrogen; template;
D O I
10.2174/157019308783498205
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this mini-review, recent chiral receptors bearing polyamine and/or polyamide functional groups are reported. Two main features for their synthesis are the source of the enantiopure nitrogenated synthons and the strategy to assemble the building blocks within the receptor architecture. Combined solutions to both problems have been carried, ranging from chemoenzymatic methods to combinatorial approaches. Topics like conformational control or templation procedures are highlighted. Applications in chiral anion molecular recognition will be also discussed.
引用
收藏
页码:33 / 46
页数:14
相关论文
共 87 条
[11]   Efficient macrocyclization of U-turn preorganized peptidomimetics:: The role of intramolecular H-bond and solvophobic effects [J].
Becerril, J ;
Bolte, M ;
Burguete, MI ;
Galindo, F ;
García-España, E ;
Luis, SV ;
Miravet, JF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (22) :6677-6686
[12]   Transition metal and organometallic anion complexation agents [J].
Beer, PD ;
Hayes, EJ .
COORDINATION CHEMISTRY REVIEWS, 2003, 240 (1-2) :167-189
[13]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[14]  
2-G
[15]  
Bianchi A, 1997, SUPRAMOLECULAR CHEMISTRY OF ANIONS, P217
[16]   Molecular recognition of oxoanions based on guanidinium receptors [J].
Blondeau, Pascal ;
Segura, Margarita ;
Perez-Fernandez, Ruth ;
de Mendoza, Javier .
CHEMICAL SOCIETY REVIEWS, 2007, 36 (02) :198-210
[17]   Enantioselective binding of dipeptides using acyclic receptors [J].
Botana, E ;
Ongeri, S ;
Arienzo, R ;
Demarcus, M ;
Frey, JG ;
Piarulli, U ;
Potenza, D ;
Gennari, C ;
Kilburn, JD .
CHEMICAL COMMUNICATIONS, 2001, (15) :1358-1359
[18]  
Braxmeier T, 2001, CHEM-EUR J, V7, P1889, DOI 10.1002/1521-3765(20010504)7:9<1889::AID-CHEM1889>3.0.CO
[19]  
2-7
[20]   Efficient syntheses of new chiral peptidomimetic macrocycles through a configurationally driven preorganization [J].
Bru, M ;
Alfonso, I ;
Burguete, MI ;
Luis, SV .
TETRAHEDRON LETTERS, 2005, 46 (45) :7781-7785