Dehalogenation of polychloroarenes with HSiEt3 catalyzed by an homogeneous rhodium-triphenylphosphine system

被引：43

作者：

Esteruelas, MA ^{[1
]}

Herrero, J

López, FM

Martín, M

Oro, LA

机构：

[1] Univ Zaragoza, Dept Quim Inorgan, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain

[2] Univ Cantabria, Dept Quim, E-39005 Santander, Spain

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 06期

关键词：

D O I：

10.1021/om9808864

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of HSiEt3, the rhodium system formed by addition, of PPh3 to [Rh(mu-Cl)(COE)(2)](2) (COE = cyclooctene) simultaneously catalyzes the dehalogenation of polychloroarenes and the formation of Et3SiCl.

引用

页码：1110 / 1112

页数：3

共 32 条

[1] ELECTROPHILIC LIGAND ABSTRACTION FROM ELECTRON-RICH IRIDIUM(I) COMPLEXES WITH ME(3)-SIOTF - EVIDENCE FOR DIRECT LIGAND ATTACK [J].

AIZENBERG, M ;

MILSTEIN, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) :411-412

[2] DIBENZO[A,E]CYCLOOCTATETRAENE IN A PROPOSED TEST FOR HETEROGENEITY IN CATALYSTS FORMED FROM SOLUBLE PLATINUM GROUP METAL-COMPLEXES [J].

ANTON, DR ;

CRABTREE, RH .

ORGANOMETALLICS, 1983, 2 (07) :855-859

[3] REDUCTIVE DECHLORINATION OF ARYL CHLORIDES CATALYZED BY PALLADIUM COMPLEXES CONTAINING BASIC, CHELATING PHOSPHINES [J].

BENDAVID, Y ;

GOZIN, M ;

PORTNOY, M ;

MILSTEIN, D .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 73 (02) :173-180

[4] OXIDATIVE ADDITION OF MONOSILANES TO PLANAR IRIDIUM(I) COMPLEXES AND CARBONYLATION OF RESULTING ADDUCTS [J].

BENNETT, MA ;

CHARLES, R ;

FRASER, PJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1977, 30 (06) :1201-1211

[5] ORGANO-SILICON CHEMISTRY .30. HOMOGENEOUS CATALYSIS BY IRIDIUM(I) COMPLEXES OF THE REACTION BETWEEN SILANES AND ALCOHOLS OR DIDEUTERIUM [J].

BLACKBURN, SN ;

HASZELDINE, RN ;

PARISH, RV ;

SETCHFIELD, JH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 192 (03) :329-338

[6]

BLAKBURN S, 1980, J CHEM RES, P170

[7] PdCl2-catalyzed reduction of organic halides by triethylsilane [J].

Boukherroub, R ;

Chatgilialoglu, C ;

Manuel, G .

ORGANOMETALLICS, 1996, 15 (05) :1508-1510

[8] RUTHENIUM(IV) SILYL HYDRIDE COMPLEXES VIA REACTION OF SILANES WITH 16-ELECTRON [RU(ETA-5-C5ME5)(P(PR-I)3)X] (X = CL, CH2SIHPH2, SIMEPH2) COMPLEXES - HYDRIDE MIGRATIONS TO AN ETA-2-SILENE LIGAND [J].

CAMPION, BK ;

HEYN, RH ;

TILLEY, TD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1201-1203

[9] MGH2 AS A REDUCING AGENT .2. REDUCTION OF ORGANIC HALIDES IN PRESENCE OF NI(O) AND PD(O) COMPLEXES [J].

CARFAGNA, C ;

MUSCO, A ;

PONTELLINI, R ;

TERZONI, G .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 54 (02) :L23-L26

[10] On the configuration resulting from oxidative addition of RX to Pd(PPh3)4 and the mechanism of the cis-to-trans isomerization of [PdRX(PPh3)2] complexes (R equals aryl, X equals halide) [J].

Casado, AL ;

Espinet, P .

ORGANOMETALLICS, 1998, 17 (05) :954-959

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