The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask

被引：43

作者：

Ikemoto, Koki ^{[1
]}

Inokuma, Yasuhide ^{[1
]}

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 33期

基金：

日本科学技术振兴机构;

关键词：

metal-organic frameworks; organozinc compounds; porous networks; single-crystal modifications; X-ray diffraction; METAL-ORGANIC FRAMEWORK; FUNCTIONALIZATION; CHEMISTRY; DESIGN; PORES;

D O I：

10.1002/anie.201002053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Organozinc addition reactions were carried out on an aldehyde within a porous coordination network (see picture) in a single-crystal-to-single-crystal fashion, and the product structure was unambiguously determined by X-ray diffraction. Moreover, a one-pot two-step reaction in a single crystal furnished an ester from an aldehyde without the network losing crystallinity. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5750 / 5752

页数：3

共 40 条

[1]

Batten S.R., 1998, ANGEW CHEM, V110, P1558, DOI DOI 10.1002/(SICI)1521-3757(19980605)110:11<1558::AID-ANGE1558>3.0.CO

[2]

2-7

[3]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[4]

2-Z

[5]

BOERSMA J, 1966, TETRAHEDRON LETT, P1521

[6] Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure [J].

Costa, Jose Sanchez ;

Gamez, Patrick ;

Black, Cory A. ;

Roubeau, Olivier ;

Teat, Simon J. ;

Reedijk, Jan .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) :1551-1554

[7] Isoreticular Metalation of Metal-Organic Frameworks [J].

Doonan, Christian J. ;

Morris, William ;

Furukawa, Hiroyasu ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (27) :9492-+

[8] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[9]

Farrusseng D., 2009, Angew. Chem., V121, P7638

[10] Metal-Organic Frameworks: Opportunities for Catalysis [J].

Farrusseng, David ;

Aguado, Sonia ;

Pinel, Catherine .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) :7502-7513

← 1 2 3 4 →