Isoreticular Metalation of Metal-Organic Frameworks

被引：258

作者：

Doonan, Christian J. ^{[1
]}

Morris, William ^{[1
]}

Furukawa, Hiroyasu ^{[1
]}

Yaghi, Omar M. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Ctr Reticular Res, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 27期

关键词：

POSTSYNTHETIC MODIFICATION; PORE-SIZE; FUNCTIONALIZATION; DESIGN;

D O I：

10.1021/ja903251e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sequential covalent transformation and metalation were performed on (Zn4O)(3)(BDC-NH2)(3)(BTB)(4) with maintenance of crystallinity and porosity. Reaction of (Zn4O)(3)(BDC-NH2)(3)(BTB)(4) with 2-pyridinecarboxaldehyde in toluene at room temperature for 5 days resulted in the formation of the extended crystalline structure (Zn4O)(3)(BDC-C6H5N2)(3)(BTB)(4), which possesses iminopyridine moieties covalently bound to the organic links of the framework. Subsequent reaction with PdCl2(CH3CN)(2) in CH2Cl2 at room temperature for 12 h yielded the metalated metal-organic framework (Zn4O)(3)(BDC-C6H5N2PdCl2)(3)(BTB)(4). Both functionatized materials retained high crystallinty and were permanently porous with high surface areas [3200 and 1700 m(2)g(-1) for (Zn4O)(3)(BDC-C6H5N2)(3)(BTB)(4) and (Zn4O)(3)(BDC-C6H5N2PdCl2)(3)(BTB)(4), respectively.]

引用

页码：9492 / +

页数：3

共 18 条

[1] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
Banerjee, Rahul
Furukawa, Hiroyasu
Britt, David
Knobler, Carolyn
O'Keeffe, Michael
Yaghi, Omar M.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) : 3875 - +
[2] Chemical modification of a bridging ligand inside a metal-organic framework while maintaining the 3D structure
Costa, Jose Sanchez
Gamez, Patrick
Black, Cory A.
Roubeau, Olivier
Teat, Simon J.
Reedijk, Jan
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (10) : 1551 - 1554
[3] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
Eddaoudi, M
Kim, J
Rosi, N
Vodak, D
Wachter, J
O'Keeffe, M
Yaghi, OM
[J]. SCIENCE, 2002, 295 (5554) : 469 - 472
[4] Covalent surface modification of a metal-organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition
Gadzikwa, Tendai
Lu, Guang
Stern, Charlotte L.
Wilson, Scott R.
Hupp, Joseph T.
Nguyen, SonBinh T.
[J]. CHEMICAL COMMUNICATIONS, 2008, (43) : 5493 - 5495
[5] Framework functionalisation triggers metal complex binding
Ingleson, Michael J.
Barrio, Jorge Perez
Guilbaud, Jean-Baptiste
Khimyak, Yaroslav Z.
Rosseinsky, Matthew J.
[J]. CHEMICAL COMMUNICATIONS, 2008, (23) : 2680 - 2682
[6] A crystalline mesoporous coordination copolymer with high microporosity
Koh, Kyoungmoo
Wong-Foy, Antek G.
Matzger, Adam J.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (04) : 677 - 680
[7] Crystals as molecules: Postsynthesis covalent functionalization of zeolitic imidazolate frameworks
Morris, William
Doonan, Christian J.
Furukawa, Hiroyasu
Banerjee, Rahul
Yaghi, Omar M.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) : 12626 - +
[8] Post-Synthesis Alkoxide Formation Within Metal-Organic Framework Materials: A Strategy for Incorporating Highly Coordinatively Unsaturated Metal Ions
Mulfort, Karen L.
Farha, Omar K.
Stern, Charlotte L.
Sarjeant, Amy A.
Hupp, Joseph T.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) : 3866 - +
[9] A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts
Shultz, Abraham M.
Farha, Omar K.
Hupp, Joseph T.
Nguyen, SonBinh T.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (12) : 4204 - +
[10] A new isoreticular class of metal-organic-frameworks with the MIL-88 topology
Surblé, S
Serre, C
Mellot-Draznieks, C
Millange, F
Férey, G
[J]. CHEMICAL COMMUNICATIONS, 2006, (03) : 284 - 286

← 1 2 →