An unusual cyanide bridging lanthanide transition metal complex that contains the one-dimensional cationic array {[(DMF)16Yb6(μ6-O)(μ3-OH)8(μ-NC)Pd(μ-CN)(CN)2]6+}∞

被引：64

作者：

Liu, JP ^{[1
]}

Meyers, EA ^{[1
]}

Shore, SG ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 21期

关键词：

D O I：

10.1021/ic9805271

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new type of lanthanide-Group(10) transition metal mixed ligand complex is produced in the redox reaction of YbCl2 with K-2[Pd(CN)(4)] . H2O in DMF. This complex consists of a cationic; chainlike array {[(DMF)(16)Yb-6(mu(6)-O)(mu(3)-OH)(8)(mu-NC)Pd(mu-CN)(CN)(2)](6+)}(infinity) in which the molecular cluster, [(DMF)(16)Yb-6(mu(6)-O)(mu(3)-OH)(8)](8+), is linked by [Pd(CN)(4)](2-) dianions with additional [Pd(CN)(4)](2-) dianions serving as counterions.

引用

页码：5410 / +

页数：3

共 5 条

[1] Heterometallic one-dimensional arrays containing cyanide-bridged lanthanide(III) and transition metals [J].