CeCl3/NaClO:: a safe and efficient reagent for the allylic chlorination of terminal olefins

被引：37

作者：

Moreno-Dorado, FJ ^{[1
]}

Guerra, FM ^{[1
]}

Manzano, FL ^{[1
]}

Aladro, FJ ^{[1
]}

Jorge, ZD ^{[1
]}

Massanet, GM ^{[1
]}

机构：

[1] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Cadiz 11510, Spain

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(03)01630-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation of allylic chlorides by reaction of terminal olefins with sodium hypochlorite in the presence of cerium trichloride heptahydrate is described. The scope, limitations and synthetic perspectives of the reaction are discussed. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：6691 / 6693

页数：3

共 15 条

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