Facile Synthesis of Isomerically Pure Fullerenols and Formation of Spherical Aggregates from C60(OH)8

被引：63

作者：

Zhang, Gang ^{[3
]}

Liu, Yun ^{[1
]}

Liang, Dehai ^{[1
]}

Gan, Liangbing ^{[2
,3
]}

Li, Yuliang ^{[3
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China

[2] Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China

[3] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 31期

关键词：

fullerenes; alcohols; self-assembly; synthetic methods; WATER-SOLUBLE FULLERENES; EFFICIENT SYNTHESIS; MIXED PEROXIDES; IN-VITRO; C-60; HYDROPEROXIDE; DERIVATIVES; CHEMISTRY; VESICLES; LIGHT;

D O I：

10.1002/anie.201001280

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Octahydroxy fullerene C60(OH)8 (see picture) is among the isomerically pure fullerenols with two to eight OH groups that were prepared by selective transformation of fert-butylperoxo groups of fullerene mixed peroxides. Since C60(OH)8 has all OH groups on the same hemisphere, it is amphiphilic and forms stable spherical aggregates in water. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：5293 / 5295

页数：3

相关论文

共 23 条

[1] Fullerenol-Cytotoxic Conjugates for Cancer Chemotherapy [J].

Chaudhuri, Padmaparna ;

Paraskar, Abhimanyu ;

Soni, Shivani ;

Mashelkar, Raghunath A. ;

Sengupta, Shiladitya .

ACS NANO, 2009, 3 (09) :2505-2514

[2] EVIDENCE OF HEMIKETALS INCORPORATED IN THE STRUCTURE OF FULLEROLS DERIVED FROM AQUEOUS ACID CHEMISTRY [J].

CHIANG, LY ;

UPASANI, RB ;

SWIRCZEWSKI, JW ;

SOLED, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (13) :5453-5457

[3] MULTIHYDROXY ADDITIONS ONTO C-60 FULLERENE MOLECULES [J].

CHIANG, LY ;

SWIRCZEWSKI, JW ;

HSU, CS ;

CHOWDHURY, SK ;

CAMERON, S ;

CREEGAN, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (24) :1791-1793

[4] FREE-RADICAL SCAVENGING ACTIVITY OF WATER-SOLUBLE FULLERENOLS [J].

CHIANG, LY ;

LU, FJ ;

LIN, JT .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (12) :1283-1284

[5] VERSATILE NITRONIUM CHEMISTRY FOR C-60 FULLERENE FUNCTIONALIZATION [J].

CHIANG, LY ;

UPASANI, RB ;

SWIRCZEWSKI, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) :10154-10157

[6] EFFICIENT SYNTHESIS OF POLYHYDROXYLATED FULLERENE DERIVATIVES VIA HYDROLYSIS OF POLYCYCLOSULFATED PRECURSORS [J].

CHIANG, LY ;

WANG, LY ;

SWIRCZEWSKI, JW ;

SOLED, S ;

CAMERON, S .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (14) :3960-3968

[7] Fullerenes as a tert-butylperoxy radical trap, metal catalyzed reaction of tert-butyl hydroperoxide with fullerenes, and formation of the first fullerene mixed peroxides C60(O)(OOtBu)4 and C70(OOtBu)10 [J].

Gan, LB ;

Huang, SH ;

Zhang, XA ;

Zhang, AX ;

Cheng, BC ;

Cheng, H ;

Li, XL ;

Shang, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13384-13385

[8] Synthesis and in vitro characterization of a tissue-selective fullerene:: Vectoring C60(OH)16AMBP to mineralized bone [J].

Gonzalez, KA ;

Wilson, LJ ;

Wu, WJ ;

Nancollas, GH .

BIOORGANIC & MEDICINAL CHEMISTRY, 2002, 10 (06) :1991-1997

[9] Activity of water-soluble fullerenes towards •OH-radicals and molecular oxygen [J].

Guldi, DM ;

Asmus, KD .

RADIATION PHYSICS AND CHEMISTRY, 1999, 56 (04) :449-456

[10]

Homma T., 2010, ANGEW CHEM, V122, P1709