Chemistry of hexanuclear rhenium chalcohalide clusters

被引：273

作者：

Gabriel, JCP ^{[1
]}

Boubekeur, K ^{[1
]}

Uriel, S ^{[1
]}

Batail, P ^{[1
]}

机构：

[1] CNRS FRE 2068, Lab Sci Mol Interfaces, F-44322 Nantes, France

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 07期

关键词：

D O I：

10.1021/cr980058k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemistry of hexanuclear rhenium chalcohalide clusters was discussed. Within the two-dimensional polymer, Re6Se8Cl2, the monomeric unit was found to be underlined using [Re6Se4iSe4/2i-a]Cl 2aSe4/2a-i. The Re-L distance as a function of the X/Q ratio was studied. The constraints imposed by the ligands and mechanochemical response of the Re6 core were also elaborated.

引用

页码：2037 / 2066

页数：30

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