Molecular organogel-forming porphyrin derivative with hydrophobic L-glutamide

被引:21
作者
Jintoku, Hirokuni [1 ]
Sagawa, Takashi [2 ]
Sawada, Tsuyoshi [1 ]
Takafuji, Makoto [1 ]
Hachisako, Hiroshi [3 ]
Ihara, Hirotaka [1 ]
机构
[1] Kumamoto Univ, Dept Appl Chem & Biochem, Kumamoto 8608555, Japan
[2] Kyoto Univ, Inst Adv Energy, Uji 6110011, Japan
[3] Sojo Univ, Dept Appl Chem, Kumamoto 8608691, Japan
关键词
D O I
10.1016/j.tetlet.2008.04.103
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An L-glutamide-functionalized tetraphenylporphyrin derivative has been newly synthesized. This can dissolve in various organic solvents to form nanofibrillar aggregates with both right-handed and left-handed chiral stacking structures among the porphyrin rings. It is also discussed on thermotropic and lyotropic phase transitions between gel and sol states. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3987 / 3990
页数:4
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