Diels-Alder addition to fluorinated single walled carbon nanotubes

被引：48

作者：

Zhang, L

Yang, JZ

Edwards, CL

Alemany, LB

Khabashesku, VN

Barron, AR

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 26期

关键词：

D O I：

10.1039/b500125k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluorinated single walled carbon nanotubes ( SWNTs) undergo a facile Diels-Alder [4+2] cycloaddition with a range of dienes resulting in a C : substituent ratio between 20 : 1 to 32 : 1; IR, Raman, AFM and C-13 NMR characterization are consistent with sidewall functionalization.

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收藏

页码：3265 / 3267

页数：3

相关论文

共 23 条

[1] Chemical generation and reactivity of C602-.: High-yield and regioselective alkylation of [60, Ih] fullerene [J].

Allard, E ;

Rivière, L ;

Delaunay, J ;

Dubois, D ;

Cousseau, J .

TETRAHEDRON LETTERS, 1999, 40 (40) :7223-7226

[2] Sequence-specific modification of guanosine in DNA by a C-60-linked deoxyoligonucleotide: Evidence for a non-singlet oxygen mechanism [J].

An, YZ ;

Chen, CHB ;

Anderson, JL ;

Sigman, DS ;

Foote, CS ;

Rubin, Y .

TETRAHEDRON, 1996, 52 (14) :5179-5189

[3] Reversible sidewall functionalization of buckytubes [J].

Boul, PJ ;

Liu, J ;

Mickelson, ET ;

Huffman, CB ;

Ericson, LM ;

Chiang, IW ;

Smith, KA ;

Colbert, DT ;

Hauge, RH ;

Margrave, JL ;

Smalley, RE .

CHEMICAL PHYSICS LETTERS, 1999, 310 (3-4) :367-372

[4] Gas-phase production of carbon single-walled nanotubes from carbon monoxide via the HiPco process: A parametric study [J].

Bronikowski, MJ ;

Willis, PA ;

Colbert, DT ;

Smith, KA ;

Smalley, RE .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2001, 19 (04) :1800-1805

[5] Solution properties of single-walled carbon nanotubes [J].

Chen, J ;

Hamon, MA ;

Hu, H ;

Chen, YS ;

Rao, AM ;

Eklund, PC ;

Haddon, RC .

SCIENCE, 1998, 282 (5386) :95-98

[6] Microwave-assisted sidewall functionalization of single-wall carbon nanotubes by Diels-Alder cycloaddition [J].

Delgado, JL ;

de la Cruz, P ;

Langa, F ;

Urbina, A ;

Casado, J ;

Navarrete, JTL .

CHEMICAL COMMUNICATIONS, 2004, (15) :1734-1735

[7]

Dresselhaus M.S., 2000, RAMAN SCATTERING MAT

[8] Solvent-free functionalization of carbon nanotubes [J].

Dyke, CA ;

Tour, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (05) :1156-1157

[9] SEQUENTIAL DOUBLE-MICHAEL ADDITIONS OF DIENOLATES WITH C-60 - RAPID ACCESS TO STERICALLY CONGESTED BUCKMINSTERFULLERENE DERIVATIVES WITH DEFINED STEREOCHEMISTRY [J].

GANAPATHI, PS ;

FRIEDMAN, SH ;

KENYON, GL ;

RUBIN, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (10) :2954-2955

[10]

Hirsch A, 2002, ANGEW CHEM INT EDIT, V41, P1853, DOI 10.1002/1521-3773(20020603)41:11<1853::AID-ANIE1853>3.0.CO