Diastereoselective hydrogenation of o-toluic acid derivatives over supported rhodium and ruthenium heterogeneous catalysts

被引：40

作者：

Besson, M ^{[1
]}

Gallezot, P ^{[1
]}

Neto, S ^{[1
]}

Pinel, C ^{[1
]}

机构：

[1] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 14期

关键词：

D O I：

10.1039/a802822b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric hydrogenation of an o-toluic acid derivative to 2-methylcyclohexanoic acid with high optical selectivity (up to 95%) was performed by using (S)-pyroglutamic acid methyl ester as a chiral auxiliary and Rh-Al2O3 as the catalyst.

引用

页码：1431 / 1432

页数：2

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