Multiple photosynthetic reaction centres using zinc porphyrinic oligopeptide-fulleropyrrolidine supramolecular complexes

被引:39
作者
Fukuzumi, Shunichi [1 ,2 ]
Saito, Kenji [1 ]
Ohkubo, Kei [1 ]
Troiani, Vincent [3 ]
Qiu, Hongjin [3 ]
Gadde, Suresh [4 ]
D'Souza, Francis [4 ,5 ]
Solladie, Nathalie [3 ]
机构
[1] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, Japan Sci & Technol Agcy JST,ALCA, Suita, Osaka 5650871, Japan
[2] Ewha Womans Univ, Dept Bioinspired Sci, Seoul 120750, South Korea
[3] Univ Strasbourg, Inst Le Bel, Lab Electrochim & Chim Phys Corps Solide, Grp Synth Multiporphyrin Syst, F-67070 Strasbourg, France
[4] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA
[5] Univ N Texas, Dept Chem, Denton, TX 76203 USA
基金
美国国家科学基金会;
关键词
PHOTOINDUCED ELECTRON-TRANSFER; FULLERENE; POLYPEPTIDES; SYSTEMS; ASSEMBLIES; MIMICKING; MIGRATION; DESIGN; ARRAYS; RINGS;
D O I
10.1039/c1cp22364j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multiple charge-separation sites have successfully been constructed using supramolecular complexes of multiporphyrinic oligopeptides [P(ZnP)(n), n = 2, 4, 8] with fulleropyrrolidine bearing a pyridine or imidazole coordinating ligand, which are organized by utilizing pi-pi interaction in addition to the coordination bond.
引用
收藏
页码:17019 / 17022
页数:4
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