Stabilized and size-tunable gold nanoparticles formed in a quaternary ammonium-based room-temperature ionic liquid under γ-irradiation

被引:51
作者
Chen, SM
Liu, YD
Wu, GZ
机构
[1] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 10039, Peoples R China
关键词
D O I
10.1088/0957-4484/16/10/061
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Colloidal gold nanoparticles were synthesized in a quaternary ammonium-based room-temperature ionic liquid (QAIL) by gamma-radiation for the first time. Transmission electron microscopy, x-ray diffraction and optical techniques were used to characterize the colloidal nanoparticles. By changing the experimental conditions, the size of the gold nanoparticles can be varied between 10 and 50 nm. It was found that gold nanoparticles coated by QAIL are very stable in dispersion.
引用
收藏
页码:2360 / 2364
页数:5
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共 33 条
[1]   Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Munro, HL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2001, (19) :2010-2011
[2]   Three-dimensional cross correlation technique: influence of multiply scattered light in the Rayleigh-Gans regime [J].
Aberle, LB ;
Staude, W ;
Hennemann, OD .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (17) :3917-3921
[3]   Contribution of radiation chemistry to the study of metal clusters [J].
Belloni, J .
RADIATION RESEARCH, 1998, 150 (05) :S9-S20
[4]   Radiation-induced synthesis of mono- and multi-metallic clusters and nanocolloids [J].
Belloni, J ;
Mostafavi, M ;
Remita, H ;
Marignier, JL ;
Delcourt, MO .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (11) :1239-1255
[5]   The use of surface-active agents in the preparation and assembly of quantum-sized nanoparticles [J].
Bognolo, G .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2003, 106 :169-181
[6]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346
[7]   Transition-metal nanoparticles in imidazolium ionic liquids: Recycable catalysts for biphasic hydrogenation reactions [J].
Dupont, J ;
Fonseca, GS ;
Umpierre, AP ;
Fichtner, PFP ;
Teixeira, SR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (16) :4228-4229
[8]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[9]   Some interesting properties of metals confined in time and nanometer space of different shapes [J].
El-Sayed, MA .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :257-264
[10]   Electrodeposition of nanocrystalline metals and alloys from ionic liquids [J].
Endres, F ;
Bukowski, M ;
Hempelmann, R ;
Natter, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (29) :3428-3430