Carbonylation of Formaldehyde with Zeolite Catalysts

被引：31

作者：

Barri, Sami A. I. ^{[1
]}

Chadwick, David ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England

来源：

CATALYSIS LETTERS | 2011年 / 141卷 / 06期

关键词：

Carbonylation; Zeolites; Glycolic acid; Formaldehyde; EXCHANGE RESIN CATALYSTS; METHYL METHOXY ACETATE; DIMETHYL ETHER; GLYCOLATE; FORMATE; HETEROPOLYACIDS;

D O I：

10.1007/s10562-011-0616-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Carbonylation of formaldehyde with carbon monoxide over zeolite catalysts has been investigated. Compared with resins (Amberlyst-15 and Amberlyst-70), and phosphotungstic acid, the zeolite catalysts especially ZSM-5 showed very high selectivity to methyl glycolate. The selectivity of ZSM-5 was maintained to high temperature up to 200 A degrees C.

引用

页码：749 / 753

页数：5

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