Influence of the ionic strength on the adsorption properties of the system dispersed aluminium oxide-polyacrylic acid

被引:46
作者
Chibowski, S [1 ]
Mazur, EO [1 ]
Patkowski, J [1 ]
机构
[1] Marie Curie Sklodowska Univ, Dept Chem, Fac Radiochem & Chem Colloids, PL-20031 Lublin, Poland
关键词
polyacrylic acid; ionic strength; zeta potential; polymer adsorption;
D O I
10.1016/j.matchemphys.2005.02.038
中图分类号
T [工业技术];
学科分类号
08 [工学];
摘要
The influence of ionic strength, pH of the solution and molecular weight of polyacrylic acid (PAA) on its adsorption and the electrical double layer (Al2O3/polyelectrolyte solution) properties have been examined. The measurements show that the adsorption increases with increasing ionic strength and molecular weight of the polymer, whereas the increase in pH reduces the adsorption. The thickness of the PAA adsorption layer onto aluminium oxide and the expansion coefficient were also calculated. The increase in ionic strength, pH of the solution and polymer molecular weight causes an increase in adsorption layer thickness and expansion coefficient of PAA. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:262 / 271
页数:10
相关论文
共 22 条
[1]
[2]
Studies of the influence of polyelectrolyte adsorption on some properties of the electrical double layer of ZrO2-electrolyte solution interface [J].
Chibowski, S ;
Krupa, M .
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2000, 21 (06) :761-783
[3]
Application of the SAXS method and viscometry for determination of the thickness of adsorbed polymer layers at the ZrO2-polymer solution interface [J].
Chibowski, S ;
Wisniewska, M ;
Marczewski, AW ;
Pikus, S .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 267 (01) :1-8
[4]
Study of the influence of poly(acrylic acid) and polyacrylamide on the electrochemical properties of the ZrO2/solution interface [J].
Chibowski, S ;
Krupa, M .
ADSORPTION SCIENCE & TECHNOLOGY, 1999, 17 (10) :813-825
[5]
Investigation of the influence of the polyvinyl alcohol adsorption on the electrical properties of Al2O3-solution interface, thickness of the adsorption layers of PVA [J].
Chibowski, S ;
Paszkiewicz, M ;
Krupa, M .
POWDER TECHNOLOGY, 2000, 107 (03) :251-255
[6]
COHEN MA, 1991, POLYM J, V23, P666
[7]
COHENSTUART MA, 1991, ADV COLLOID INTERFAC, V34, P477
[8]
Crummett W.B., 1963, J. Am. Water Works Assoc, V55, P209, DOI [10.1002/j.1551-8833.1963.tb01016.x, DOI 10.1002/J.1551-8833.1963.TB01016.X]
[9]
Evaluation of the adsorption trends of a low molecular-weight polyelectrolyte with a site-binding model [J].
Dupont, L ;
Foissy, A .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1996, 110 (03) :235-248
[10]
Fleer G., 1993, Polymers at interfaces, DOI 10.1002/pi.1995.210360115