A highly rigid ditopic conjugate with orthogonal coordination axes and its zinc(II) and copper(II) complexes

被引：11

作者：

Champin, Benoit ^{[1
]}

Sartor, Valerie ^{[1
]}

Sauvage, Jean-Pierre ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, Fac Chim,LC 3, Lab Chim Organominerale,UMR 7177, F-67070 Strasbourg, France

来源：

NEW JOURNAL OF CHEMISTRY | 2008年 / 32卷 / 06期

关键词：

D O I：

10.1039/b713367g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly rigid ditopic ligand has been prepared which consists of a terpy fragment connected in the back to a phen nucleus via a 1,4-phenylene linker. The chemical structure of the presently reported ligand is such that the coordination axes of the two chelates are orthogonal to one another. The reaction of this phen-terpy conjugate with zinc(II) surprisingly affords in good yield a dinuclear complex in spite of the tension of the generated structure, whereas coordination of copper(II) centres to the two-chelate ligand enables the formation of the trinuclear complex also.

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页码：1048 / 1054

页数：7

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