A theory of morphotropic phase boundary in solid-solution systems of perovskite-type oxide ferroelectrics

被引:93
作者
Ishibashi, Y [1 ]
Iwata, M [1 ]
机构
[1] Nagoya Univ, Sch Engn, Dept Appl Phys, Nagoya, Aichi 4648603, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1999年 / 38卷 / 2A期
关键词
morphotropic phase boundary; dielectric susceptibility; piezoelectric constants; free energy; Landau theory;
D O I
10.1143/JJAP.38.800
中图分类号
O59 [应用物理学];
学科分类号
摘要
The origin of the appearance of the morphotropic phase boundary in perovskite-type oxide solid solution systems is clarified on the basis of a Landau-type free-energy function expressed in terms of polarization and strain components. The dielectric susceptibilities and piezoelectric constants are shown to increase in the vicinity of the morphotropic phase boundary.
引用
收藏
页码:800 / 804
页数:5
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