Preparation of both antipodes of enantiopure inherently chiral calix[4]crowns

被引：72

作者：

Cao, YD ^{[1
]}

Luo, J ^{[1
]}

Zheng, QY ^{[1
]}

Chen, CF ^{[1
]}

Wang, MX ^{[1
]}

Huang, ZT ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 01期

关键词：

D O I：

10.1021/jo0354185

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Both antipodes of enantiopure inherently chiral calix[4]crown derivatives were successfully obtained through separation of their BINOL diastereomeric derivatives of corresponding racemates using preparative TLC instead of conventional HPLC methods. Such a result provides a basis for future study of chiral recognition and asymmetric catalysis with inherently chiral calixrene derivatives.

引用

页码：206 / 208

页数：3

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