Preparation and photochemical properties of p-phenylene oligomers encapsulated within faujasite Y

被引：5

作者：

Alvaro, M

Ferrer, B

García, H

Leyva, A

机构：

[1] UPV, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] Univ Politecn Valencia, Dept Quim, Valencia 46022, Spain

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2004年 / 6卷 / 02期

关键词：

D O I：

10.1039/b314477a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phenylene oligomers have been prepared by ship-in-a-bottle synthesis inside palladium containing basic zeolites by homo-coupling of 1,4-phenylenediboronic acid. Product analysis and "in situ" IR spectroscopy support the formation of oligomers of three to five phenylene rings. The encapsulated oligomers emit the characteristic blue light upon excitation and laser flash photolysis reveals the formation of long-lived transient decaying in hundreds of mus that has been attributed to the corresponding triplet excited state.

引用

页码：201 / 204

页数：4