Carbon dioxide fixation - Copper(II) and zinc(II) complexes can fix atmospheric carbon dioxide

被引：131

作者：

Kong, LY

Zhang, ZH

Zhu, HF

Kawaguchi, H

Okamura, T

Doi, M

Chu, Q

Sun, WY ^{[1
]}

Ueyama, N

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448585, Japan

[3] Osaka Univ, Dept Macromol Sci, Toyonaka, Osaka 560, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 28期

关键词：

carbon dioxide fixation; copper; networks; NMR spectroscopy; zinc;

D O I：

10.1002/anie.200500587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Carbonato bridges from atmospheric carbon dioxide: The copper(II) and zinc(II) complexes of the novel imidazole-containing polyamine ligand N1-(2-aminoethyl)-N1-(2-imidazolethyl) ethane-1,2-diamine are found to fix carbon dioxide by hydration to μ3-carbonate ligands. This is revealed by IR and solid-state 13C NMR spectroscopic and X-ray crystallographic studies of the two-dimensional complexes (see picture). © 2005 Wiley-VCH Verlag GmbH £ Co. KGaA.

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收藏

页码：4352 / 4355

页数：4

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